Activated Alumina, as a high-performance adsorbent, has shown outstanding value in chemical, environmental protection, energy and other fields.
1. Technical characteristics: porous structure and functional adaptability
High-quality activated alumina has bimodal pore distribution (large pore volume + mesoporous channel), and its key indicators are far beyond those of ordinary adsorbent materials:
Specific surface area: 300-600m²/g (5-10 times that of ordinary alumina), nano-scale micropores provide massive adsorption sites;
Pore capacity: 0.4-0.8cm³/g, supports rapid mass transfer, and improves adsorption efficiency by 40%;
Mechanical strength: compressive strength of spherical particles > 120N/particle, wear resistance > 1000 times;
Thermal stability: withstands high temperature of 800℃ and does not collapse, suitable for high-temperature gas drying;
Chemical stability: Resistant to acid and alkali corrosion (pH range 3-12), suitable for complex working conditions.
2. Preparation process: Precisely regulate pore structure
The preparation of high-quality activated alumina requires combining nanomaterial engineering and chemical thermodynamics:
Sol-gel method:
Aluminum salt (AlCl₃ or Al(NO₃)₃) is used as raw material, and polyvinyl alcohol (PVA) is added as a dispersant to form a uniform sol through pH regulation;
After supercritical drying (avoiding channel collapse), a mesoporous material with a specific surface area of >500m²/g was obtained, and the adsorption rate was increased by 35%.
Template agent pore making technology:
Polymethyl methacrylate (PMMA) microspheres were added as hard templates, and ordered macropores (pore size 50-200nm) were formed after calcination;
Combined with soft template agents (such as cetyltrimethylammonium bromide, CTAB) to regulate mesoporous (2-50nm) distribution to achieve a graded pore structure.
Industrialization optimization:
A continuous spray drying tower is used to control the feeding speed (5-10mL/min) and hot air temperature (350-400℃) to produce spherical particles with uniform particle size (Φ3-8mm) in batches.
3. Application scenarios: Cross-domain value mining
New energy field
Lithium battery separator coating: high-purity alumina (above 4N) is used as a ceramic coating material to improve the heat resistance of the separator (without shrinkage of 400℃) and ensure battery safety;
Hydrogen fuel cell: Modified alumina support is supported by platinum catalyst to improve the efficiency of hydrogen oxidation reaction.
Environmental protection engineering
Flue gas desulfurization: γ-Al₂O₃ supported metal oxides (such as CuO/Al₂O₃), achieving SO₂ catalytic oxidation (conversion rate >95%);
Wastewater treatment: Nanoalumina composite membrane (pore size <2nm) retains heavy metal ions (Pb²⁺, Cr⁶⁺), and the treatment efficiency reaches 99.8%.
Pharmaceutical Industry
Drug drying: In a vacuum belt dryer, the moisture adsorption rate of activated alumina is three times that of ordinary desiccant;
Vaccine carrier: mesoporous alumina is loaded with antigen proteins to improve the intensity of immune response.
Activated Alumina, as a high-performance adsorbent, has shown outstanding value in chemical, environmental protection, energy and other fields.
1. Technical characteristics: porous structure and functional adaptability
High-quality activated alumina has bimodal pore distribution (large pore volume + mesoporous channel), and its key indicators are far beyond those of ordinary adsorbent materials:
Specific surface area: 300-600m²/g (5-10 times that of ordinary alumina), nano-scale micropores provide massive adsorption sites;
Pore capacity: 0.4-0.8cm³/g, supports rapid mass transfer, and improves adsorption efficiency by 40%;
Mechanical strength: compressive strength of spherical particles > 120N/particle, wear resistance > 1000 times;
Thermal stability: withstands high temperature of 800℃ and does not collapse, suitable for high-temperature gas drying;
Chemical stability: Resistant to acid and alkali corrosion (pH range 3-12), suitable for complex working conditions.
2. Preparation process: Precisely regulate pore structure
The preparation of high-quality activated alumina requires combining nanomaterial engineering and chemical thermodynamics:
Sol-gel method:
Aluminum salt (AlCl₃ or Al(NO₃)₃) is used as raw material, and polyvinyl alcohol (PVA) is added as a dispersant to form a uniform sol through pH regulation;
After supercritical drying (avoiding channel collapse), a mesoporous material with a specific surface area of >500m²/g was obtained, and the adsorption rate was increased by 35%.
Template agent pore making technology:
Polymethyl methacrylate (PMMA) microspheres were added as hard templates, and ordered macropores (pore size 50-200nm) were formed after calcination;
Combined with soft template agents (such as cetyltrimethylammonium bromide, CTAB) to regulate mesoporous (2-50nm) distribution to achieve a graded pore structure.
Industrialization optimization:
A continuous spray drying tower is used to control the feeding speed (5-10mL/min) and hot air temperature (350-400℃) to produce spherical particles with uniform particle size (Φ3-8mm) in batches.
3. Application scenarios: Cross-domain value mining
New energy field
Lithium battery separator coating: high-purity alumina (above 4N) is used as a ceramic coating material to improve the heat resistance of the separator (without shrinkage of 400℃) and ensure battery safety;
Hydrogen fuel cell: Modified alumina support is supported by platinum catalyst to improve the efficiency of hydrogen oxidation reaction.
Environmental protection engineering
Flue gas desulfurization: γ-Al₂O₃ supported metal oxides (such as CuO/Al₂O₃), achieving SO₂ catalytic oxidation (conversion rate >95%);
Wastewater treatment: Nanoalumina composite membrane (pore size <2nm) retains heavy metal ions (Pb²⁺, Cr⁶⁺), and the treatment efficiency reaches 99.8%.
Pharmaceutical Industry
Drug drying: In a vacuum belt dryer, the moisture adsorption rate of activated alumina is three times that of ordinary desiccant;
Vaccine carrier: mesoporous alumina is loaded with antigen proteins to improve the intensity of immune response.